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Adhesive Industry Market Research Report


Release time:

2014-03-08

 

 

An adhesive is a material that exhibits excellent bonding performance, forming a thin film between the surfaces of two objects and firmly joining them together. It is typically formulated from a combination of components such as adhesion-promoting substances, curing agents, toughening agents, fillers, diluents, and modifiers.

 

1. The adhesive substance, also known as the binder, is the fundamental component of adhesives, responsible for their bonding action. Its properties determine the performance, applications, and usage conditions of the adhesive. Commonly used adhesive substances include various resins, rubber-based materials, and natural macromolecular compounds.

2. Curing agent. A curing agent is a component that accelerates the solidification of bonding materials through chemical reactions; it can enhance the cohesive strength of the adhesive layer. Some resins used in adhesives, such as epoxy resin, cannot themselves become hard solids without the addition of a curing agent. The curing agent is also a key ingredient in adhesives, and its properties and dosage play a crucial role in determining the performance of the adhesive.

3. Toughening agents. Toughening agents are components used to enhance the toughness of the adhesive bond layer after the adhesive has cured, thereby improving its impact resistance. Commonly used toughening agents include dibutyl phthalate and dioctyl phthalate.

4. Diluent, also known as a solvent, primarily serves to reduce the viscosity of adhesives, making them easier to handle and enhancing their wettability and fluidity. Commonly used organic solvents include acetone, benzene, and toluene.

5. Fillers. Fillers generally do not undergo chemical reactions in adhesives. They can increase the viscosity of the adhesive, reduce its coefficient of thermal expansion, minimize shrinkage, and enhance its impact toughness and mechanical strength. Commonly used types include talc powder, asbestos powder, and aluminum powder.

6. Modifiers. Modifiers are components added to adhesives to enhance specific performance characteristics and meet particular requirements. For example, coupling agents can be added to increase bonding strength; additionally, anti-aging agents, preservatives, anti-mold agents, flame retardants, and stabilizers can also be incorporated individually as needed.

 

There are many types of adhesives, and there are also various classification methods. Commonly used ones include:

1. Classification by Chemical Composition: Adhesives can be categorized into organic adhesives and inorganic adhesives. Organic adhesives, in turn, are divided into synthetic adhesives and natural adhesives. Synthetic adhesives include resin-based, rubber-based, and composite types; natural adhesives encompass animal, plant, mineral, and natural rubber-based adhesives. Inorganic adhesives, based on their chemical composition, include various types such as phosphate-based, silicate-based, sulfate-based, and borate-based adhesives.

 

Adhesives classified according to the nature of the bonding substance

glue

 

 

sticky

 

 

agent

There is

 

machine

 

Class

Combine

Become

Class

Tree

Fat

Type

Thermosets: phenolic resin, epoxy resin, unsaturated polyester, polyurethane, urea-formaldehyde resin, and others

Thermoplastics: Polyvinyl acetate, polyvinyl chloride-vinyl acetate copolymer, polyacrylate, polystyrene, polyamide, alkyd resin, cellulose, saturated polyester, and others.

Rubber types: reclaimed rubber, styrene-butadiene rubber, silicone rubber, chloroprene rubber , polysulfide rubber, etc.

Hybrid types: phenol-formaldehyde-polyvinyl alcohol acetal, phenol-formaldehyde-chloroprene rubber, epoxy-phenol-formaldehyde, epoxy-polythioether rubber, and others.

sky

However

Class

Glucose derivatives: starch, soluble starch, aleurone, gum arabic, sodium alginate, etc.

Amino acid derivatives: plant protein, casein, blood protein, gelatin, fish glue, sodium alginate, and others.

Natural resins: lignin, tannins, rosin, shellac, raw lacquer

Asphalt, asphaltic glue

None

machine

Class

Silicate Adhesives

Phosphate-based adhesives

Borates

Sulfur glue

Silica sol

 

2. Classified by form: Adhesives can be divided into liquid adhesives and solid adhesives. They include solution-type, emulsion-type, paste-like, adhesive films, adhesive tapes, powders, adhesive granules, and glue sticks, among others.

3. Classified by application: They can be divided into three major categories—structural adhesives, non-structural adhesives, and special-purpose adhesives (such as high-temperature resistant, ultra-low-temperature resistant, conductive, thermally conductive, magnetically conductive, sealing, and underwater adhesives).

4. Classified by application method: There are adhesives such as room-temperature curing type, thermosetting type, hot-melt type, pressure-sensitive type, and rewettable type.

 

Adhesives can be used in fields such as construction, wood processing, automotive, packaging, and bookbinding. The following sections will focus on architectural adhesives and wood adhesives.

 

Building Adhesive

Adhesives are primarily used in architectural decoration and renovation processes for bonding panels, pre-treating wall surfaces, applying wallpaper, and adhering ceramic wall and floor tiles, various types of flooring, and carpets. In architectural decoration, the use of adhesives not only demonstrates considerable strength but also offers a range of comprehensive properties, including water resistance, sealing performance, elasticity, and impact resistance. These characteristics help enhance the quality of architectural decoration, increase aesthetic appeal and comfort, improve construction techniques, and boost both the efficiency and quality of building projects.

Adhesives used for architectural decoration and renovation can be categorized into water-based adhesives, solvent-based adhesives, and other types of adhesives. Among these, water-based adhesives include polyvinyl acetate emulsion adhesives (white latex), water-soluble polyvinyl alcohol construction adhesives, and other water-based adhesives (such as 108 glue and 801 glue). Solvent-based adhesives encompass rubber adhesives, polyurethane adhesives (PU adhesives), and other solvent-based adhesives.

 

Types of Architectural Adhesive Products and Their Standards

(1) Polyvinyl acetate emulsion adhesives are adhesives whose main component is polyvinyl acetate emulsion or its modified derivatives.

(2) Water-soluble polyvinyl alcohol architectural adhesives refer to water-soluble polymer architectural adhesives prepared by chemically modifying polyvinyl alcohol as the main raw material.

(3) Rubber adhesives are adhesives made using natural rubber or synthetic rubbers (such as chloroprene rubber, nitrile rubber, silicone rubber, styrene-butadiene rubber, etc.) as the adhesive base.

(4) Polyurethane adhesives are adhesives whose primary raw material is polyurethane resin or its modified derivatives.

 

Performance and Applications of Commonly Used Adhesives in Construction

Types

Feature

Main uses

Thermoplastic synthetic resin Adhesive

Polyvinyl alcohol formaldehyde-based adhesives

It has high adhesive strength and exhibits good resistance to water, oil, abrasion, and aging.

It can be used as the main film-forming substance in coatings, or mixed with cement mortar to enhance the adhesion of the mortar layer. It is suitable for pasting wallpaper, wall coverings, tiles, and other materials.

Polyvinyl acetate adhesives

Cures quickly at room temperature, exhibits high bonding strength, and boasts excellent toughness and durability of the adhesive layer. It is resistant to aging, non-toxic, odorless, and not easily flammable or explosive. It’s low in price but has poor water resistance.

Widely used for bonding various non-metallic materials such as wallpaper, glass, ceramics, plastics, fiber fabrics, stone, concrete, and gypsum; it can also serve as a cement reinforcing agent.

Vinyl alcohol adhesive (glue) )

Water-soluble adhesive, non-toxic, easy to use, with moderate bonding strength.

Suitable for bonding plywood, wallpaper, paper, and more.

Thermosetting synthetic resin adhesive

Epoxy resin adhesives

High bonding strength, low shrinkage, corrosion resistance, excellent electrical insulation, water resistance, and oil resistance.

Bonds metal products, glass, ceramics, wood, plastics, leather, cement products, fiber products, and more.

Phenolic resin adhesives

High bonding strength, fatigue resistance, heat resistance, and resistance to weathering.

For bonding metal, ceramic, glass, plastic, and other non-metallic materials.

Polyurethane Adhesives

Good adhesion, fatigue resistance, oil resistance, water resistance, acid resistance, excellent toughness, outstanding low-temperature performance, and room-temperature curability—but poor heat resistance.

Suitable for bonding plastics, wood, leather, and other materials, particularly ideal for applications requiring water resistance, acid resistance, and alkali resistance.

Synthetic rubber

Adhesive

Acrylonitrile-butadiene rubber adhesive

Good elasticity and weather resistance, excellent resistance to fatigue, oil, and solvents, and good heat resistance. It exhibits good miscibility but has poor adhesion and forms a film slowly.

Suitable for bonding rubber to rubber, rubber to metal, and rubber to fabrics in oil-resistant components. Particularly well-suited for bonding soft polyvinyl chloride materials.

Neoprene adhesive

High adhesion and cohesion strength, with excellent flame resistance, oil resistance, and solvent resistance. Poor storage stability and miscibility.

For structural bonding or bonding between different materials, such as rubber, wood, ceramics, asbestos, and other diverse materials.

Polysulfide rubber adhesive

Excellent elasticity and adhesion. Good oil resistance and weather resistance, impermeable to gases and vapors, and highly resistant to aging.

As a sealant Also used for repairing, surface sealing, and anti-slip treatments of road surfaces, flooring, and concrete. Suitable for sealing in seaports, docks, and underwater structures.

Silicone rubber adhesive

Good UV resistance, aging resistance, heat resistance, and corrosion resistance; excellent adhesion; waterproof and shockproof.

Suitable for bonding metals, ceramics, concrete, and certain plastics. Particularly well-suited for installing window and door glass, as well as for sealing tile and rock joints in underground structures such as tunnels and subways.

 

         Wood adhesive

The development of wood adhesives has had a positive impact on the growth of the wood industry, including particleboard and fiberboard production. It has enabled the full utilization of small-diameter logs, branch and limb materials, thinning wood, and wood-processing residues, thereby enhancing the overall wood utilization rate and improving wood performance. Adhesives have become a critical factor determining the level of advancement in particleboard and fiberboard manufacturing. The implementation of new production processes, the enhancement of production efficiency, and the improvement of working conditions are all closely linked to adhesives and bonding technologies.

The most prominent feature of wood adhesives is their large consumption volume. The cost, variety, and quality of wood adhesives directly affect the cost, quality, and application scope of engineered wood products. Consequently, the vast majority of China’s wood-processing enterprises have established their own adhesive production workshops, with urea-formaldehyde resin adhesive, phenol-formaldehyde resin adhesive, and melamine resin adhesive being the primary types of adhesives they produce. Meanwhile, as the variety of wood-based composite products continues to expand and quality requirements keep rising, specialized adhesive manufacturing enterprises are emerging one after another.

 

[Artificial Synthetic Adhesives]

(1) Adhesives for the engineered wood panel industry

Urea-formaldehyde resin, along with phenol-formaldehyde resin and melamine-formaldehyde resin, is known as one of the three major adhesives used in the engineered wood panel industry; among these, urea-formaldehyde resin is the most important and dominant variety.

① Urea-formaldehyde (UF) resin adhesive

Urea-formaldehyde resin adhesives are renowned for their low cost, simple production process, ease of use, light color that does not contaminate the finished products, excellent bonding performance, and wide range of applications. However, artificial boards made with urea-formaldehyde resins generally suffer from two major problems: first, the formaldehyde gas released by these boards pollutes the environment; second, their water resistance—especially their resistance to boiling water—is poor. Scholars both domestically and internationally have conducted extensive research on ways to reduce formaldehyde emissions from urea-formaldehyde resin-based boards. They have proposed new synthesis processes involving a sequence of strong acid–weak acid–alkali (neutral) conditions; controlling the molar ratio of formaldehyde to urea; adopting a secondary polycondensation process for formaldehyde; adding formaldehyde scavengers to the finished adhesive; and performing post-processing treatments after the boards have been manufactured. To improve their water resistance, researchers have employed methods such as copolymerization and blending with modifying agents to alter the resin’s water-resistant properties, and have also introduced certain amounts of isocyanates (PMDI) or borax into the synthesis process.

② Phenol-formaldehyde (PF) resin adhesive

Phenolic resin adhesives are made from readily available raw materials and exhibit excellent weather resistance. However, they have several drawbacks, including high hot-pressing temperatures, long curing times, and stringent requirements for the moisture content of wood veneers. To reduce costs without significantly compromising performance, modifiers and substitutes can be introduced. Additionally, accelerating the curing speed and lowering the curing temperature represent key research directions for phenolic resin adhesives.

③ Melamine-formaldehyde (MF) resin adhesive

Melamine-formaldehyde resin adhesives exhibit excellent water resistance, weather resistance, high bonding strength, and high hardness. They also cure faster than phenolic resins. Moreover, melamine-formaldehyde resin films maintain their color and gloss even at high temperatures. However, melamine-formaldehyde resin adhesives have several drawbacks: they are relatively expensive, brittle and prone to cracking, lack sufficient flexibility, and suffer from poor storage stability. By introducing a modifier—methyl glucoside—into melamine-formaldehyde resins, not only can the storage stability of the resin be enhanced, but the cost can also be reduced. Additionally, this modification improves the resin’s plasticity, increases its flowability, and lowers the content of free formaldehyde.

④ Polyurethane (PU) Adhesive

Polyurethane adhesives are broadly categorized into two major types: polyisocyanates and polyurethanes. They are reactive adhesives with outstanding bonding performance and have become a focal point of research in this field. Currently, they are widely used in particleboard, oriented strand board, medium-density fiberboard, engineered wood products, various composite boards, and surface decorative panels, with their usage rapidly increasing. In particular, they exhibit excellent performance when applied to man-made boards made from agricultural crop residues. Previously, these adhesives were mainly used for bonding the core layers; however, in recent years, their application has gradually expanded to cover the entire board. Nevertheless, due to the high cost of polyurethane adhesives and their significant content of organic solvents—which can pollute the environment and pose health risks—widespread adoption has been hindered. In recent years, there has been growing interest in the development and application of low-cost, high-performance, environmentally friendly waterborne polyurethanes.

⑤ Thermoplastic resin adhesive

Research on the manufacture of engineered wood panels using various plastics or recycled plastics (thermoplastic resins) as adhesives in China began in the early 1990s. Production lines for thermoplastic resin-based plywood (wood-plastic composite plywood) and formaldehyde-free solid wood composite flooring based on this type of plywood have been successively built and put into operation.